GAS PRODUCTION IN SEALED LEAD ACID BATTERIES
A. Hydrogen is produced within lead-acid
batteries when charging takes to the electrolysis of water.
The rate of hydrogen production may be calculated
using the formula,
Hydrogen = 0.456 x I litres
per hour per cell where I is the charging Amps.
The fraction of hydrogen produced
from electrolysis that is actually generated for emission will depend
on the recombination efficiency of the cell, and may be calculated
using the formula,
H = 0.456 x I x (1-z) litres/hour/cell
where z is the recombination efficiency of the cell.
B. Example calculation:
i. If the recombination efficiency of the cell is
100% then any hydrogen evolved will be at a very slow rate, from
the corrosion of internal battery components. This type of hydrogen
evolution will be very dependent on the mode of use, but for continuous
float charge an approximate figure is:
100 millilitres/Ampere hour capacity/cell/Annum.
E.g. NP 24-12 would produce approximately 14.4 litres
per year.
ii. If the recombination efficiency is only 85%
and the overcharge current is 10 Amps then the volume of hydrogen
will be 0.684 litres/hour/cell.
C. Recombination efficiency of Yuasa Batteries.
NP SERIES - it can be seen that NP batteries have practically 100%
recombination efficiency of the charging current is below 0.01 CA.
As the maximum overcharge current in normal float conditions is
less than 0.004C it can be seen that condition B i. applies for
NP batteries in normal float service.
NB. In the event of malfunction of the charging
systems to produce overcharge the rate of hydrogen production may
be calculated as in B ii. above.
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